Assembly of CdS Quantum Dots onto Hierarchical TiO2 Structure for Quantum Dots Sensitized Solar Cell Applications
نویسندگان
چکیده
Quantum dot (QD) sensitized solar cells based on Hierarchical TiO2 structure (HTS) consisting of spherical nano-urchins on transparent conductive fluorine doped tin oxide glass substrate is fabricated. The hierarchical TiO2 structure consisting of spherical nano-urchins on transparent conductive fluorine doped tin oxide glass substrate synthesized by hydrothermal route. The CdS quantum dots were grown by the successive ionic layer adsorption and reaction deposition method. The quantum dot sensitized solar cell based on the hierarchical TiO2 structure shows a current density JSC = 1.44 mA, VOC = 0.46 V, FF = 0.42 and η = 0.27%. The QD provide a high surface area and nano-urchins offer a highway for fast charge collection and multiple scattering centers within the photoelectrode.
منابع مشابه
حساس سازی همزمان سلولهای خورشیدی نقاط کوانتومی متشکل ازفوتوآند نانوبلوری TiO2 با نانوذرات CdS و PbS و بررسی تأثیر نقاط کوانتومی PbS بر عملکرد سلول خورشیدی
In this research, CdS and PbS quantum dots were applied as the light sensitizers in TiO2 based nanostructured solar cells. The PbS quantum dots could absorb a wide range of the sunlight spectrum on earth due to their low bandgap energy. As a result, the cell sensitization is more effective by application of both CdS and PbS quantum dots sensitizers. The TiO2 nanocrystals were synthesized throug...
متن کاملSILAR Sensitization as an Effective Method for Making Efficient Quantum Dot Sensitized Solar Cells
CdSe quantum dots were in situ deposited on various structures of TiO2 photoanode by successive ionic layer adsorption and reaction (SILAR). Various sensitized TiO2 structures were integrated as a photoanode in order to make quantum dot sensitized solar cells. High power conversion efficiency was obtained; 2.89 % (Voc=524 mV, Jsc=9.78 mA/cm2, FF=0.56) for the cells that sensitized by SILAR meth...
متن کاملThe Study of Metal Sulfide as Efficient Counter Electrodes on the Performances of CdS/CdSe/ZnS-co-sensitized Hierarchical TiO2 Sphere Quantum Dot Solar Cells
The effects of using different counter electrode metal sulfides on the performances of solar cells made with CdS/CdSe/ZnS quantum dots co-sensitized onto hierarchical TiO2 spheres (HTSs) used as photo-electrode are reported. The HTS in the QDSSCs is composed of an assembly of numerous TiO2 spheres made by the solvolthermal method. The photoelectrical performance of HTS/CdS/CdSe/ZnS coupled to C...
متن کاملCdS/CdSe Co-Sensitized Solar Cell Prepared by Jointly Using Successive Ion Layer Absorption and Reaction Method and Chemical Bath Deposition Process
CdS/CdSe quantum dots co-sensitized TiO2 solar cell was prepared by combining the successive ion layer absorption and reaction (SILAR) method and chemical bath deposition (CBD) method for the fabrication of CdS and CdSe quantum dots, respectively. The effect of CdSe deposition time on the solar cell performance was investigated. It was found that the optimized deposition time for CdSe was 3 h, ...
متن کاملSynthesis and Characterization of Graphene-ZnO Nanocomposite and its Application in Photovoltaic Cells
In this paper, we present a simple method for preparation of graphene-ZnO nanocomposites (G-ZnO). The method is based on thermal treatment of the graphene oxide (GO)/ZnO paste which reduces the graphene oxide into the graphene and leads to the formation of the G-ZnO nanocomposite. The structure, morphology and optical properties of synthesized nanocomposites are characterized with XRD, FESEM, F...
متن کامل